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is achieved using a Diels-Alder reaction of cyclopentadiene functions. This approach provides polymer supported zirconocene with a homogeneous distribution of active sites. The zirconocene-containing supported catalyst forms spherical beads and is active when combined with MAO at promoting PE formation. The polymerization activity was 5 30% that of the homogeneous catalyst, producing 5 to 66 105 g PE/Zr h. The molecular weight of the PE prepared was 6 106, and the molecular weight distribution ratio was 2.9 3.4. Rietmuller and coworkers38 recently reported locating zirconocene-containing groups on hyperbranched polysilanes for the purpose of producing stereoregular polymers. The polycarbosilane dendrite is hydroborated at the terminal vinyl groups and then the zirconocene moiety is attached. PP was produced using this dendrite in toluene at a propylene pressure of 5 bar yielding PP in moderate yields with [mmmm] values about 35%. The proposed zirconocene site is pictured in structure 7. rdlc pdf 417 PDF417 Barcode Creating Library for RDLC Reports | Generate ...
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